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Q.

A cube of side 5 cm made of iron and having a mass of 1500 gm, is heated from 2500C to 400oC.  The  specific heat  for  iron  is 0.12 cal/gm/°C and the coefficient of volume expansion is 3.5×10–5/°C. The change in internal energy of the cube is: (atmospheric pressure = 105 N/m2)

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a

320 kJ

b

282 kJ   

c

141 kJ   

d

423 kJ

answer is B.

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Detailed Solution

Q = Ms\Delta \theta

1 cal/gm = 4200 J/kg.

Q = 1500 \times {10^{ - 3}} \times 0.12 \times 4200 \times (400 - 25)

= 15×12×42×375×10-1  = 283500 J

Q = 283.5 kJ

W=PV=105Vγt=105×125×10-6×3.5×10-5×375=0.164J it is very very small compare to Q

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