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Q.

A current of 965 A is passed for 100sec between inert electrodes in 500 mL solution of 2M CuSO4. The molarity of solution after electrolysis would be(assume no change in volume)

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a

1M

b

4M

c

2M

d

0.5M

answer is B.

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Detailed Solution

According to Faraday's first law: 

Cu2++2e-Cu  (n=2) w= zit  w= E it nF n=965×10096500×2=0.5 intial moles = 500 ×10-3×2 =1  moles of Cu left = 1-0.5 =0.5  Molarity after electrolysis = 0.5500×10-3=1M

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