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Q.

A current of 9.65 A is passed for 3 hours between nickel electrodes in 0.5 L of a 2 M solution of Ni(NO3)2. The molarity of the solution after electrolysis would be (atomic mass of Ni = 58)

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a

0.46 M

b

1.25 M

c

0.92 M

d

0.625 M

answer is C.

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Detailed Solution

Number of coulombs of current passed = 9.65 ×3600 ×3 = 104220

Number of moles of electrolyte reduced = 104220×0.596500=0.54

Moles of Ni(NO3)2 remaining after electrolysis = 1-0.54 =0.46

Concentration = 0.46 ×2 =0.92

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A current of 9.65 A is passed for 3 hours between nickel electrodes in 0.5 L of a 2 M solution of Ni(NO3)2. The molarity of the solution after electrolysis would be (atomic mass of Ni = 58)