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Q.

A cylinder of ideal gas is closed by an 8 kg movable piston (area 60cm2) as shown in figure. Atmospheric pressure is 100kPa. When the gas is heated from 30°C , to 100°C the piston rises by 20cm. The piston is then fixed in its place and the gas is cooled back to 30°C . Let ΔQ1 be the heat added to the gas in the heating process and ΔQ2 the heat lost during cooling. Then the value of ΔQ2ΔQ2will be :

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a

Zero

b

136 J

c

-136 J

d

-68 J

answer is B.

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Detailed Solution

The gas pressure = Weightofpiston  Areaofcross-section + atm.pressure 
=8×9.860×104+1.00×105N/m2=1.13×105N/m2
During the heating process, the internal energy is changed by U1 and work W1 , is
done.
Therefore,ΔQ1=ΔU1+ΔW1=ΔU1+P.dV
=ΔU1+1.13+1050.20×60×104=ΔU1+136J
During the cooling process, no work is done as volume is constant, ΔW=0.
Hence, ΔQ2=ΔU2. But ΔU2
But ΔU2 is negative as the temperature decreases, and since the gas
returns to its original temperature, ΔU2=ΔU1
Hence,ΔQ1ΔQ2
=ΔU1+136ΔU1=+136J

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A cylinder of ideal gas is closed by an 8 kg movable piston (area 60cm2) as shown in figure. Atmospheric pressure is 100kPa. When the gas is heated from 30°C , to 100°C the piston rises by 20cm. The piston is then fixed in its place and the gas is cooled back to 30°C . Let ΔQ1 be the heat added to the gas in the heating process and ΔQ2 the heat lost during cooling. Then the value of ΔQ2−ΔQ2will be :