Q.

A definite amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain temperature and 0.50 atm pressure. NH4HS decomposes to give NH3 and H2S and at equilibrium total pressure in flask is 0.84 atm. The equilibrium constant for the reaction is (atm2):

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a

0.30

b

0.18

c

0.17

d

0.11

answer is D.

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Detailed Solution

NH4HSNH3+H3S(g)a                     0.5a-x                  0.5+x    xPT=0.5+2x=0.84X=0.17KP=(0.67)(0.17)0.1139

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