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Q.

A definite volume of pure ammonia (NH3) gas is passed through a series of electric sparks by which the volume becomes 90 ml. The increase in volume is due to formation of nitrogen (N2) and hydrogen (H2) gases. All the gases finally present are washed with dilute sulphuric acid solution, by which the volume of gases becomes 80 ml. All the volumes are measured at the same temperatures and pressure Which of the following statement(s) is/are correct regarding the original ammonia sample?

The volume of NH3 gas taken was 40 ml.

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a

The volume of NH3 gas taken was 40 ml.

b

The volume of NH3 gas taken was 50 ml.

c

Only 80% of NH3 gas decomposed into N2 and H2 gases

d

Only 20% of NH3 gas decomposed into N2 and H2 gases

answer is B, C.

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Detailed Solution

NH312N2+32H2

V2 3V2

V2+3V2=2V=80

V=40

VNH3 left =10mL

VNH3 taken =50mL

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