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Q.

A diatomic ideal gas is heated at constant volume until the pressure is doubled and again heated at constant pressure until volume is doubled. The average molar heat capacity for whole process is -

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a

13R6

b

19R6

c

23R6

d

17R6

answer is B.

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Detailed Solution

Let initial pressure, volume, temperature be P0, V0, T0 indicated by state A in P-V diagram. The gas is then isochorically taken to state 
B (2P0 , V0 , 2T0) and then taken from state B to state C(2P0 , 2V0 , 4T0) isobarically.

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Total heat absorbed by 1 mole of gas
ΔQ=CV2P0T0+CP4T02T0=52RT0+72R×2T0=192RT0
Total change in temperature from state A to C is
ΔT=3T0 molar heat capacity =ΔQΔT=192RT03T0
=196R

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