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Q.

a) Dinitrogen pentoxide can be prepared by dehydrating nitric acid with  P4O10.
b) On heating  Pb(NO3)2  at 400oC,   a brown-coloured gas with diamagnetic nature is obtained.
c)  68%(w/w)HNO3  can be concentrated to 98% by using conc.  H2SO4.
d) The familiar brown ring test for nitrates depends on the ability of Fe+3   to reduce nitrates to nitric oxide. 
The correct statements are 
 

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a

a and c only

b

a,c and d only 

c

c and d only 

d

a,b and c only

answer is A.

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Detailed Solution

b – On heating   Pb(NO3)2 at 4000C, a brown colored  NO2  gas with paramagnetic nature is obtained 
d – The brown ring test or nitrate test is a reduction reaction. The nitrate is reduced to nitric oxide (NO) by ferrous (II) ions from ferrous sulphate, which is oxidised to ferric (III) ions.
 

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