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Q.

(a) Draw the structure of main product formed in the following reaction:  

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(b) In the following reaction, A and B are

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OR

(a)  Arrange the following in increasing order of dipole moment:

Toulene (I), m-dichlorobenzene (II), o-dichlorobenzene (III), p-dichlorobenzene (IV)

(b) Why chloroform is stored in closed dark coloured completely filled bottles. Give reason.

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Detailed Solution

(a)  The products are But-2-ene and But1-ene 

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(b)   The product A is 4-Chloro Acetophenone

        The product B is 2-Chloro Acetophenone

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                                                                         OR

(a) The increasing order of dipole moment is

 IV < I < II < III

(b) To  avoid the formation of phosgene, chloroform is stored away from light and air.
In dark coloured bottles, no light can enter. Thus, oxidation of chloroform to phosgene can be avoided.
Thus, chloroform is stored in closed dark coloured bottles.
2CHCl3+O2 Sunlight 2COCl2+2HCl

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