(a) Draw the structure of major monohalogen product formed in the following reaction:

(b) Arrange the following in increasing order of boiling point:
(i)CH3CH2CH2CH2Br
(ii)(CH3)3.Br
(iii) (CH3)2C.Br

OR

(a) Write the IUPAC name of

(b) Which compound in the following pair undergoes faster SN1 reaction.

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Detailed Solution

(B) (CH3)2C.Br < (CH3)2.CHCH2.Br < CH3CH2CH2CH2Br

OR

(a) 2-chloro-3-methylbutane (b) reacts faster by SN1 mechanism as it is a tertiary halide and it produces a stable tertiary carbocation.
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