Q.

A first order reaction 75% completed in 120 min at 300 K temperature and in 40 min at 320 K. The activation energy of reaction is ______kcal/mol.   
(given : ln 3 = 1.1)

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answer is 11.

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Detailed Solution

At 300 K,       t0.5=1202=60  min 
At 320 K           t0.875=1.5×40=60  min
ln   6020=Ea2×103(13001320)
             Ea=10.56  cal/mol

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