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Q.

A fixed quantity of an ideal gas can be expanded from an initial state to a certain volume through two different processes (i) PV2=constant and (ii) P=KV2 where K is a constant.

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a

Final temperature in (i) will be greater than that in (ii)

b

Final temperature in (ii) will be greater than that in  (i)

c

Heat is given to the gas in  (i)  rejected by the gas in (ii)

d

 Heat is given to the gas in (ii) rejected by the gas in  (i)

answer is B, D.

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Detailed Solution

For the process (i) PV2= constant

nRTVV2= constant

Tα1 V

for the process (ii) P=KV2

Therefore nRTV=kV2 TV3

 On increasing volume, final temperature in process (ii) is greater than that in process (i) . So option 2 is right .

Now, for process PVx=constant, molar heat capacity, C=Rγ-1-R1-x

 for process (i) C1=Cv-R

for process 

(ii) C2=Cv-R(-2-1)=Cv+R3 C2>C1 and (ΔT)ii is positive and Ti is negative . So option 4 is right .

 

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