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Q.

A flask of gaseous CCl4 was weighted at measured temperature and pressure. CCl4 was replaced by O2 at the same temperature and pressure. The mass of the CCl4 vapor will be

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a

Five times as heavy as O2

b

One fifth heavy as compared to O2

c

No change in mass

d

None of these

answer is A.

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Detailed Solution

The molar mass of CCl4(M1)=154 (or)

The molar mass of O2(M2)=32

CCl4 when compared toO2

12 + 71 × 2 

12 + 142

= 154 > 32

5 times as heavy has O2

15432=4.8125 5 times as heavy as O2

Hence CCl4 is approximately 5 times heavier than oxygen.

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