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Q.

(A) For the reduction of esters into alcohols, Ni/H2 is preferred than LiAlH4.
(R) LiAlH4 is more expensive than Ni/H2

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a

Both ‘A’ and ‘R’ are true and ‘R’ is the correct explanation of ‘A’.

b

‘A’ is false and ‘R’ is false

c

Both ‘A’ and ‘R’ are true and ‘R’ is not the correct explanation of ‘A’

d

‘A’ is true and ‘R’ is false

answer is A.

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Detailed Solution

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EstersLiAlH4Alcohols

Carboxylic acids, esters and amides are less reactive, and thus, cannot be reduced by catalytic hydrogenation, except under extreme conditions.

This means that LiAlH4 is an expensive reducing agent.

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(A) For the reduction of esters into alcohols, Ni/H2 is preferred than LiAlH4.(R) LiAlH4 is more expensive than Ni/H2