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Q.

A galvanic at 298 K: MnO4+8H++5Fe2+Mn2++5Fe3++4H2O

Given: EMnO4,Mn2+,H+Pt=1.51V and EFe3+,Fe2+Pt=0.77V

The standard cell potential is

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a

0.74 V

b

-0.74 V

c

-2.28 V

d

2.28 V

answer is C.

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Detailed Solution

Ecell =1.51V0.77V=0.74V

The potential difference between the cathode and anode is the standard cell potential. Cell Potentials can be viewed for further details. At 298 K, 1 atm, and using 1 M solutions, the standard potentials are all measured.

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