Q.

A galvanic cell is constructed using two Hydrogen electrodes. Emf is highest when the PH of the solutions at anode and cathode is _____ and _____ respectively.

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a

3, 2

b

4, 1

c

2, 0

d

1, 3

answer is A.

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Detailed Solution

pH= - log[H+]

Ecell=Ecello-0.05912log [reduction][oxidation] 

For option -1 

pH=4 when anode[H+] = 10-4 pH= 1 when Cathode [H+]=10-1 Ecell= -0.05912log10-410-1= 0.0885V

Similarly for 

option -2  Ecell = -0.059V 

option -3 Ecell = 0.03 V

option- 4 Ecell = 0.059 V 

 

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