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Q.

A gas (Molar mass = 280g/Mol) was burnt in excess O2 in a constant volume calorimeter and during combustion the temperature of the calorimeter is increased from 298 K to 298.45 K. If the heat capacity of a calorimeter is 2.5 kJ K1 and the enthalpy of combustion of gas is 9 kJ mol1 then the amount of gas burnt is ______g. 

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a

35

b

45

c

55

d

65

answer is A.

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Detailed Solution

ΔH=ΔU+0 (W=0 at constant volume)

X/280 moles give 2.5 x 0.45KJ
 1 mole give =2.5 x 0.45 x 280 / X = 9
X = 35 g

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