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Q.

A gas Cl2 at 1 atm is bubbled through a solution containing a mixture of 1 M Br- and 1 M F- at 25oC. If the reduction potential is F > Cl > Br, then: 

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a

Cl will oxidise Br and not F

b

Cl will oxidise F and not Br

c

Cl will oxidise both Br and F

d

Cl will reduce both Br and F

answer is A.

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Detailed Solution

Z > Y > X (Non-metals like F2>Cl2>Br2)

So, Y will oxidise X but not Z-

Z will oxidise both X- and Y-

X can't oxidise Y- or Z-

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