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Q.

A gaseous mixture enclosed in a vessel consists of one mole of a gas A with  γ=(53)  and some amount of gas B  with  γ=(75) at a temperature T. The gases A and B do not react with each other and are assumed to be ideal. Find the number of moles of the gas B if  γ  for the gaseous mixture is  (1913) .

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answer is 2.

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Detailed Solution

AS FOR IDEAL GAS   CpCu=R   and   γ=(CPCυ)
SO   Cυ=R(γ1)
   Cν1=R(53)1=32RCν2=R(75)1=52R
 Now from conservation of energy,
 i.e,           ΔU=ΔU1+ΔU1(μ1+μ2) Cνmix ΔT=[μ1(Cυ)1+μ2(Cυ)2]ΔT

i.e,           (Cυ)mix=μ1(Cυ)1+μ2(Cυ)2μ1+μ2

We have  136R=1×32R+μ252R1+μ2=(3+5μ2)R2(1+μ2)

13+13μ2=9+15μ2μ2=2 moles

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