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Q.

A group 13 element ‘X’ reacts with chlorine gas to produce a compound XCl3. XCl3  is electron deficient and easily reacts with NH3 to form Cl3XNH3 adduct; however, XCl3 does not dimerize. X is

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a

B

b

Al 

c

In
 

d

Ga 

answer is A.

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Detailed Solution

BCl3 do not dimerize due ot absence of vacant d- orbitals.

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