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Q.

A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number n. The excited atom can make a transition to the first excited state by successively emitting two photons of energies 10.2 and 17.0 eV respectively. Alternately, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25 eV and 5.95 eV respectively. Determine the value of ‘n’. (Ionization energy of H-atom = 13.6eV)

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answer is 6.

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Detailed Solution

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Z2(141n2)=2;Z2(191n2)=34

(10.20+17.00)eV=13.6Z2×1221n2...(1)

(4.24+5.95)eV=13.6Z2×1321n2...(2)

On dividing equation 1 and 2, 

1.18=n24n290.18n2=6.6n2=36n=6

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A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number n. The excited atom can make a transition to the first excited state by successively emitting two photons of energies 10.2 and 17.0 eV respectively. Alternately, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25 eV and 5.95 eV respectively. Determine the value of ‘n’. (Ionization energy of H-atom = 13.6eV)