Q.

(a) (i) Write the disproportionation reaction of H3PO3.
(ii) Draw the structure of XeF4.
(b) Account for the following:
(i) Although Fluorine has less negative electron gain enthalpy yet F2 is strong oxidizing agent.
(ii) Acidic character decreases from N2O3 to Bi2O3 in group 15.
(c) Write a chemical reaction to test sulphur dioxide gas. Write chemical equation involved.

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Detailed Solution

(a) (i) H3PO33H3PO4+PH3
(ii) Question Image
(b) (i) Fluorine has small size low bond dissociation enthalpy which makes it a strong oxidizing agent.
(ii) On going down the group the size of elements increases. It decreases the electronegativity. Due to which acidic character decreases.
(c) 5SO2+2MnO4+2H2O5SO42+4H++2Mn2+

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