Q.

A litre of buffer solution contains 0.1 mole of each of NH3  and NH4Cl . On the addition of  0.02 mole of HCl  by dissolving gaseous HCl , the pH of the solution is found to be ______×10-3  (Nearest integer)
[ Given :-  pKb(NH3)=4.745
log2=0.301
log3=0.477
T=298  K]

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answer is 9079.

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Detailed Solution

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NH3+HClNH4Cl   0.1               0.02                    0.1   0.08                                        0.12
P.H=PKb+log[ salt ][ Base ]=4.745+log0.120.08=4.745+log32=4.745+(0.4770.301)=4.745+0.176=4.921PH=144.921=9.079=9079×103

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A litre of buffer solution contains 0.1 mole of each of NH3  and NH4Cl . On the addition of  0.02 mole of HCl  by dissolving gaseous HCl , the pH of the solution is found to be ______×10-3  (Nearest integer)[ Given :-  pKb(NH3)=4.745log2=0.301log3=0.477T=298  K]