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Q.

A low pressures, the compression factor of CO2 having constant value of molar volume

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a

increases with increase in temperature

b

decreases with increase in temperature

c

remains constant with change in temperature

d

is greater than one

answer is A.

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Detailed Solution

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According to van der Waals equation,
(P+aV2)(Vb)=RT
At very low pressure, volume (V) is very large. Hence, a / V2 is so small that it can be neglected. Similarly, volume correction term .b can also be neglected in comparison to V. Thus, the above equation reduces to PV = RT. Hence, at very low pressure a real gas behaves like ideal gas.

therefore volume increases with increase in temperature.
 

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