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Q.

A manometer attached to a flask contains with ammonia gas have no difference in mercury level initially as shown in diagram. After sparking into the flask, ammonia is partially dissociated as 2NH3(g)N2(g)+3H2(g) now it have difference of 6 cm in mercury level in two columns, what is partial pressure of H2(g) at equilibrium? 
 

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a

27 cm Hg

b

9 cm Hg

c

18 cm Hg

d

None of these

answer is A.

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Detailed Solution

                              2NH3(g)N2(g)+3H2(g) Before sparking       76           0                0 After sparking         76-2x     x                3x at equilibrium
Increase in pressure 2x = 6 ; x =3 cm Hg
Partial pressure of H2 =3 x 3 =9 cm Hg

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