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Q.

A metal (A) on heating in nitrogen gas gives compound B. B on treatment with H2O gives a colorless gas which when passed through CuSO4 the solution gives a dark blue-violet-colored solution. A and B respectively, are:

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a

Na and Na3N

b

Na and NaNO3

c

Mg and Mg3N2

d

Mg and Mg(NO3)2

answer is C.

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Detailed Solution

The metal (A) should be magnesium, which it reacts with nitrogen to give compound (B) Mg3N2. The obtained Mg3N2 upon treatment with  H2O gives ammonia NH3 which is a colorless gas. When this ammonia NH3 passed through CuSO4 solution it forms dark blue-violet complex 

[Cu(NH3)4]SO4. ​     

3Mg+N2Mg3N2

Mg3N2+6H2O3Mg(OH)2+2NH3     

CuSO4+4NH3[Cu(NH3)4]SO4

Hence the correct option is (C).

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