Q.

A metal has fcc lattice. The edge length of the unit cell is 404 pm. The density of themetal is 2.72 g cm–3. The molar mass of the metal is ___ g mol–1. (2 digits)
(NA is Avagadro’s constant = 6.02 × 1023 mol–1)

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answer is 27.

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Detailed Solution

Given, FCC lattice
We need to find the molar mass of the metal,

d=2.72gcm−3 density of crystal
z is the number of particles that make up a unit cell.
M = Molecular weight
a = Edge length of unit cell at 404 p.m.
NA=6.022×1023
cubic unit cell density
d=ZMa3 NA
Z=4 for an FCC.
M=da3 NAZM=2.72×404×10-103×6.02×10234=27 g/mol

Therefore, the correct answer is 27.

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