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Q.

A metal M and its compound can give the following observable changes in a sequence of reactions,

M Very dilute HNO3 Colourless solution and no gas is enolved  

 Aqueous NaOH  White  precipitate  Excess NaOH(aq) Colourless  solution 

OH-H2S  White  precipitate 

The metal M can be.

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a

Zn

b

Pb

c

Mg

d

Sn

answer is C.

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Detailed Solution

Zinc nitrate is created when dil nitric acid and zinc react.

4Zn+10HNO3 dil 4ZnNO32+NH4NO32+3H2O

Sodium nitrate and a white precipitate of zinc hydroxide are created when zinc nitrate and sodium hydroxide combine.

2NaOH+ZnNO322NaNO3+Zn(OH)2

Sodium zincate is created when zinc hydroxide and extra sodium hydroxide react.

 Zn(OH)2+2NaOH excess Na2ZnO2 sodium zincate +2H2O

A white precipitate of zinc sulphide is created when hydrogen sulphide and sodium zincate interact.

Na2ZnO2 sodum zincate +H2SZnS white precipitate +2NaOH+2H2O

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