Q.

A metal M reacts with N2 to give a compound ‘A’ M3N. ‘A’ on heating at high temperature gives back ‘M’ and ‘A’ on reacting with H2O gives a gas ‘B’. ‘B’ turns CuSO4 solution blue on passing through it. A and B can be

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a

Al and NH3

b

Li and NH3

c

Na and NH3

d

Mg and NH3

answer is B.

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Detailed Solution

Lithium forms nitride on heating with nitrogen;Lithium nitride gives ammonia when heated with H2O. Ammonia gas forms tetrammine copper complex with CuSO4 solution.

6Li  +  N2     2Li3N Li3N + 3H2O   3LiOH  +  NH3 CuSO4 + 4NH3    CuNH34SO4

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