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Q.

A metal salt with the formula  MCl2 crystallizes from water to form a solid with the composition MCl2.6H2O. The equilibrium vapour pressure of water above this solid at 290 K is 0.1 atm. The value of ΔrGin kcal mol1for the reaction,

MCl2.6H2O(s) MCl2(s)+6H2O(g) at 0.1 atm pressure is _______.

Given R=2 cal K1mol1, lnx=2.3logx

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Detailed Solution

0.1 atm is the equilibrium pressure of the system. At equilibrium  ΔrG=0

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A metal salt with the formula  MCl2 crystallizes from water to form a solid with the composition MCl2.6H2O. The equilibrium vapour pressure of water above this solid at 290 K is 0.1 atm. The value of ΔrGin kcal mol−1for the reaction,MCl2.6H2O(s)⇌ MCl2(s)+6H2O(g) at 0.1 atm pressure is _______.Given R=2 cal K−1mol−1, lnx=2.3logx