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Q.

A mixture containing 9 grams of oxalic acid and 9.2 grams of formic acid  is treated with Conc. H2SO4 . The evolved gaseous mixture is passed through Caustic potash. Number of atoms present in the remaining gaseous product will be NA =Avagadro's  number 

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a

0.3 NA

b

1.2 NA

c

0.6NA

d

2.2 NA

answer is C.

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Detailed Solution

(i)    46g                                                                 28gHCOOH   ΔConc.H2SO4  CO+H2O      9.2g                            5.6g
                                                   
(ii)  COOH2ΔConc.H2SO4  CO+CO2+H2O                                        90 gm of oxalic acid gives 28gm of CO and 44 gm of CO29 gm of oxalic acid gives 2.8 gm of CO and 4.4 gm of CO2Total weight of  CO =5.6g + 2.8gTotal weight of CO2  = 4.4gCO2 is absorbed by caustic potash Water is absorbed by conc.H2SO4                                                                  
 WCO =8.4g ;  28g of CO contain  2NA atoms 8.4g of CO contain   0.6NA atoms

 

 


                 

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