Q.

A mixture of 0.4 mole of H2(g) and 0.2 mole of Br2(g) is heated  in a container of volume 1 litre at 700 K to achieve an equilibrium. The equilibrium constant  [Kc] is  2.5×109. Find out the value of [Br2][HBr]×1010. Here [Br2] and [HBr] are the concentrations of Br2(g) and HBr(g) respectively at equilibrium.

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answer is 8.

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Detailed Solution

H2+Br22HBr

0.4   0.2        0 ……..Initially
0.2    a         0.4 …….at eq

Kc=(0.4)20.2×a         2.5×109=0.8a   a=3.2×1010       [Br2][HBr]=3.2×10100.4=8×1010      [Br2][HBr]×1010=8 

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