Q.

A mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic KOH, it gives

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a

1-Propene

b

A mixture of 1-propene and 2-propene

c

Isopropylene

d

2-Propene

answer is A.

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Detailed Solution

When alkyl halides are treated with alcoholic KOH, an elimination reaction (dehydrohalogenation) occurs. This reaction removes a hydrogen atom and a halogen atom, forming a double bond and resulting in an alkene. This is a β-elimination reaction where the halogen atom is removed from the α-carbon, and the hydrogen atom is removed from the β-carbon.

In this case:

1. 1-Chloropropane (CH3CH2CH2Cl):

When treated with alcoholic KOH, it undergoes elimination to give propene:

CH3CH2CH2Cl → CH3CH=CH2 + HCl

2. 2-Chloropropane (CH3CHClCH3):

When treated with alcoholic KOH, it also undergoes elimination to give propene:

CH3CHClCH3 → CH3CH=CH2 + HCl

Final Product:

Both 1-chloropropane and 2-chloropropane produce the same product, which is propene (CH3CH=CH2), through dehydrohalogenation with alcoholic KOH.

The reaction gives propene (CH3CH=CH2) as the product.

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A mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic KOH, it gives