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Q.

A mixture of 1 mole of H2O and 1 mole of CO is taken in a 10 litre container and heated to 725 K. At equilibrium 40% of water by mass reacts with carbon monoxide according to the equation: CO(g)+H2O(g)CO2(g)+H2(g). The equilibrium constant Kc×102for the reaction is _____________. (Nearest integer)

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answer is 44.

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Detailed Solution

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                                                              CO(g)+H2O(g) CO2(g)+H2(g)
Initial concentrations  (mole.lit1)   0.1       0.1                  0                 0
Reacted to reach equilibrium            -0.04     -0.04             +0.04       +0.04
Reacted to reach equilibrium            0.06        0.06              0.04          0.04
Equilibrium constant KC=[CO2]1[H2]1[CO]1[H2O]1
        =(0.04)(0.04)(0.06)(0.06)        =0.4444
Nearest integer of KC×102=44

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