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Q.

A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc.H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight of the remaining product at STP will be ____ grams.

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answer is 2.89.

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Detailed Solution

HCOOHn=2.346=0.05 H2SO4 CO0.05moles+H2O  (COOH)2n=4.590=0.05 H2SO4 CO0.05+CO20.05+H2O 

Gaseous mixture formed is CO and CO2. When it is passed through KOH, only CO2 is absorbed. So the remaining gas is CO. 

So, the no. of moles of gaseous product CO= 0.05+0.05=0.1mole

Weight of CO=0.1×28=2.8g

Hence, the correct answer 2.8 g.

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