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A mixture of A and B show positive deviation from Raoult’s law when

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A – B interaction is stronger than A – A and B – B interaction

A – B interaction is weaker than A – A and B – B interaction

$Δ V_{m i x} < 0$ , $Δ S_{m i x} = 0$

$Δ V_{m i x} = 0$ , $Δ S_{m i x} > 0$

answer is B.

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When A – B interaction is weaker than A – A and B – B interaction, then the mixture of A and B shows positive deviation.

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