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Q.

A mixture of boron trichloride and hydrogen is subjected to silent electric discharge to form 'A' and HCI. 
'A' is mixed with NH3; and heated to 200°C to form 'B'. The formula of 'B' is

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a

H3BO3

b

B2O3

c

B2H6

d

B3N3H6

answer is D.

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Detailed Solution

When boron trifluoride undergoes in electric discharge in the presence of hydrogen gas, it forms B2H6 (A) and HCl.

2BCl3+6H2Electric dischargeB2H6(A)+6HCl

When B2H6 (A) heated with ammonia at 200°C, it forms B3N3H6 (B) and hydrogen gas. 

3B2H6+6NH3200°C2B3N3H6(B)+12H2

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