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Q.

A mixture of Nitrogen and Hydrogen (1:3 mole ratio) is at an initial pressure of 200atm. If 20% of the mixture reacts by the time equilibrium is reached, the equilibrium pressure of the mixture is

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a

160 atm

b

180 atm

c

170 atm

d

Data insufficient

answer is B.

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Detailed Solution

The equilibrium reaction for the preparation of ammonia is

N2+3H2200  atm2NH30

Initial(atm): 200         0 

Equilibrium: 200 - x    2x

200-20 atm        

 2×20 atm

=180 atm

Therefore, equilibrium pressure of the mixture N2 and H2is 180 atm.

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