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Q.

A mixture of two colourless substances was dissolved in water. When gaseous Cl2 was passed through the solution, containing small quantity of CCl4 a violet colour developed in organic layer. Addition of BaCl2 to the original solution give a white precipitate. The mixture contains :

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a

salts of iodide and sulphate

b

salts of sulphate and chloride

c

salts of bromide and chloride

d

salts of nitrate and chloride

answer is C.

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Detailed Solution

MgI2 and MgSO4are both present in the combination.
Magnesium sulphate and barium chloride react to produce white ppt of barium hydroxide.
White ppt of magnesium hydroxide is created when sodium hydroxide and magnesium iodide combine. Magnesium sulphate and NaOH react to produce ppt with the same colour.
Brown ppt is created when magnesium salts and chlorine gas combine.

Cl2+2KI2KCl+I2 (violet); 

BaCl2+SO42BaSO4 (white ppt.) 

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