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Q.

A nitrogen containing compound dissolves in 10% aq. sulphuric acid.

The Hinsberg test (C6H5SO2Cl in base) gives a solid product that is not soluble in 10% aq. NaOH. Which of the following would best fit these facts?

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a

N,N-Dimethylaniline, C6H5NCH32

b

N-Methylbenzamide, C6H5CONHCH3

c

N-Methylaniline, C6H5NHCH3

d

Benzylamine, C6H5CH2NH2

answer is C.

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Detailed Solution

2∘ amines reacts with Hinsberg reagent and forms solid compound but do not soluble in due to absence of acidic H on N.

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