Q.

A non - volatile solute (A) is dissolved in a volatile solvent (B). The vapour pressure of resultant solution is PS .The vapour pressure of pure solvent is PB°  . If X is the mole fraction , then the correct one of the following is

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a

PB0=PSXB

b

PS=PB0XB

c

PS=PB0XA

d

PB0=PSXA

answer is C.

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Detailed Solution

If a solution has a non volatile solute in a volatile solvent then the vapor pressure of resultant solution depends on mole fraction of solvent present in it.Vapour pressure of solution, PS=PB0.XB .
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A non - volatile solute (A) is dissolved in a volatile solvent (B). The vapour pressure of resultant solution is PS .The vapour pressure of pure solvent is PB°  . If X is the mole fraction , then the correct one of the following is