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Q.

A non-linear triatomic gas is 50%  dissociates into individual atoms. Ignoring, the vibrational degree of freedom and any further dissociation , the gas behaves as if the number of degree of freedom is

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a

4.75

b

3.25

c

4.25

d

3.75

answer is B.

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Detailed Solution

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nmix=n1+n2(i)
Let no be the initial number of atoms dissociated n1=3no/2
Not dissociated n2=no/2
nmix =n1+n2=2nofmix =n1f1+nf2nmix=3.75fmix =32no×3+no2×62no

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