Q.

“A” obtained by Ostwald’s method involving air oxidation of NH3, upon further air oxidation produces “B”, “B” on hydration forms an oxoacid of Nitrogen along with evolution of “A”. The oxoacid also produces “A” and given positive brown ring test. Identify A and B, respectively.

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a

NO2, N2O4

b

NO2N2O5

c

N2O3,NO2

d

NO,NO2

answer is C.

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NH3+O2NOO2NO2H2OHNO2+NO

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“A” obtained by Ostwald’s method involving air oxidation of NH3, upon further air oxidation produces “B”, “B” on hydration forms an oxoacid of Nitrogen along with evolution of “A”. The oxoacid also produces “A” and given positive brown ring test. Identify A and B, respectively.