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Q.

(A) On heating with P4O10, carboxylic acids give anhydrides. 
(R) Carboxylic acids on reduction with LiAlH4 give alcohols.

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a

Both (A) and (R) are true but (R) is not the correct explanation of (A)

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

(A) is true but (R) is false

answer is B.

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Detailed Solution

Carboxylic Acid Reactions: Assertion-Reason

(A) On heating with P4O10, carboxylic acids give anhydrides. [Correct]

(R) Carboxylic acids on reduction with LiAlH4 give alcohols. [Correct]

  • P4O10 is a strong dehydrating agent and when heated with carboxylic acids, it removes water leading to the formation of acid anhydrides.
  • LiAlH4 is a powerful reducing agent, reducing carboxylic acids efficiently to primary alcohols.
  • Both statements are correct, but (R) does not explain (A); they address different reactions of carboxylic acids.

Conclusion: Both (A) and (R) are true, but (R) is not the explanation for (A).

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