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Q.

(A) :One molar aqueous solution (d=1gm/cc) has always higher concentration than one molal.
(R) :The molality of a solution does not depends on temperature whereas molarity depends.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is B.

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Detailed Solution

 We know,Mass of solventVolume of solution <1 Mass of solvent < Volume of solution 1Mass of solvent>1Volume of solution Molality > Molarity
Molality is inversely proportional to weight of solvent, where weight is independent of temperature.
Molarity is inversely proportional to volume, where volume depends on temperature thus molarity depends to temperature.
Hence, correct option is: (B) Both (A) and (R) are true and (R) is not the correct explanation of (A)

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