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Q.

A open ended mercury manometer is used to measure the pressure exerted by a trapped gas as shown in the figure. Initially manometer shows no difference in mercury level in both column as shown in diagram.

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After sparking the container, 'A' dissociates according to following reaction

A(g)B(g)+3C(g)

If pressure of Gas "A" decreases to 0.9 atm, then (Assume temperature to be constant and is 300 K) the wrong statement is

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a

total pressure increases by 0.3 atm

b

total pressure increases by 22.3 cm of Hg

c

total pressure increases to 1.3 atm

d

difference in mercury level is 228 mm of Hg

answer is C.

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Detailed Solution

PT=(1+3×)=1+3×0.1=1.3atmΔP=0.2atm or 76×0.3cm of Hg or 760×0.3mm of Hg

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