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Q.

A pale yellow solid (A) having crown shape is heated with concentrated H2SO4, it gives
suffocating smell of gas B, which is passed through moistened with starch iodide paper and turn it into blue. The gas B and solid A are respectively.

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a

SO3 and S2N2

b

SO2 and S8

c

SO3 and SO2

d

SO3 and S8

answer is B.

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Detailed Solution

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Sulpuhric acid is a oxidizing agent. 2H2SO4+S8(g)3SO2+H2O(l) 
Gas B is SO2 
Solid A is S8

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