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Q.

A particular reaction has a rate constant of 1.3×10-2 s-1. Find out the ratio of t1/2t99.9

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a

1/10

b

100

c

1

d

10

answer is B.

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Detailed Solution

K=1.3×102 s-1 t1/2     so  1st order  t1/2=0.693k t99.2%=2.303klog(1000.8) t1/2t99.2%=6.693k2.303klog1000.8 0.6932.303×log(125) =0.6932.303×2.091/10

Therefore, the correct option is (B).

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