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Q.

A polytropic process for an ideal gas is represented by equation PVn = constant. If g is ratio of specific heats% (CpCv), then value of n for which molar heat capacity of the process is negative, is given as:

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a

γ > n

b

γ > n >1

c

none, as it is not possible

d

n > γ

answer is B.

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Detailed Solution

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C = Rγ-1-Rn-1 = R(n-γ)(n-1)(γ-1)

C is negative if γ > n > 1.

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