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Q.

A potassium salt (F) gives a brown coloured gas with dil.HCl in presence of air and forms a dark brown colored ring (G) with ferrous sulfate and acetic acid at the junction of liquids. The salt (F) decolourises the acidified KMnO4  solution. Choose the correct option(s) for the (F) and (G):

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a

Addition of potassium iodide solution to the salt solution(F) followed by freshly prepared starch solution and acidification with acetic acid produces blue colour.

b

(G) is paramagnetic complex [Fe(H2O)5(NO2)]2+

c

addition of acidified Co(NO3)2 to the salt solution (F) produces a yellow coloured low spin complex.

d

Anion of F can be removed using thiourea and NH2SO3H in acidic medium during detection of NO3 ion using Brown ring test.

answer is A, C, D.

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Detailed Solution

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FKNO2   &   Gis  [Fe(H2O)5(NO)]2+ , Co(NO3)2+KNO2+H+K3[Co(NO2)6]

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